Issue 11, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Gas-phase pyrolysis of 1-(2-azidophenyl)imidazole

Alexander J. Blake,   Bernard A. J. Clark,   Hamish McNab  and  Craig C. Sommerville  

Abstract

Flash vacuum pyrolysis (FVP) of the azide 4 leads to imidazo[1,2-a]benzimidazole 8 exclusively, via highly regioselective insertion of the triplet nitrene intermediate 5 into the 2-CH bond of the imidazole ring. The X-ray crystal structure and NMR spectroscopic properties of 8 are discussed in detail.

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Article information

DOI
https://doi.org/10.1039/A700457E
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 1605-1608

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Gas-phase pyrolysis of 1-(2-azidophenyl)imidazole

A. J. Blake, B. A. J. Clark, H. McNab and C. C. Sommerville, J. Chem. Soc., Perkin Trans. 1, 1997, 1605 DOI: 10.1039/A700457E

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