Issue 9, 1997

Bicyclo[3.3.1]nonanes as synthetic intermediates. Part 20.1 Asymmetric synthesis of the indolizidine alkaloids monomorine I and indolizidine 223AB

Abstract

Total syntheses of the indolizidine alkaloids monomorine I and indolizidine 223AB have been achieved by starting from the chiral cis-2,5-disubstituted pyrrolidine or cis-2,6-disubstituted piperidine obtained from the asymmetric cleavage of 8-azabicyclo[3.2.1]octan-3-one or 9-azabicyclo[3.3.1]nonan-3-one at the ‘fork head’.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 1315-1322

Bicyclo[3.3.1]nonanes as synthetic intermediates. Part 20.1 Asymmetric synthesis of the indolizidine alkaloids monomorine I and indolizidine 223AB

T. Momose, M. Toshima, S. Seki, Y. Koike, N. Toyooka and Y. Hirai, J. Chem. Soc., Perkin Trans. 1, 1997, 1315 DOI: 10.1039/A607981D

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