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Issue 3, 1997
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Total syntheses of (+)-asperlin, (+)-acetylphomalactone and (5S,6S,7R,8S)-asperlin based on the kinetic resolution of 2-furylmethanols

Abstract

The total syntheses of (+)-asperlin 1, (+)-acetylphomalactone 2 and (5S,6S,7R,8S)-asperlin 3 have been achieved employing the kinetic resolution of unsymmetric divinylmethanol using modified Sharpless reagents, which produced two oxidation products, as a key step.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1997, 317-322
Article type
Paper

Total syntheses of (+)-asperlin, (+)-acetylphomalactone and (5S,6S,7R,8S)-asperlin based on the kinetic resolution of 2-furylmethanols

Z. Yang, X. Jiang, Z. Wang and W. Zhou, J. Chem. Soc., Perkin Trans. 1, 1997, 317
DOI: 10.1039/A603209E

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