Issue 5, 1997
From the journal:

Mendeleev Communications

Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with dibromobis(phosphine)palladium(II) - sodium alkoxide system

Andrei N. Vedernikov,   Marat D. Sayakhov  and  Boris N. Solomonov  

Abstract

Dibromobis(phosphine)palladium(ii) complexes, PdBr2 (L)2 [L = PPh3, P(p-Tol)3], react with cyclohexane and an alcoholic solution of sodium alkoxide, NaOR (R = Me, Et, Pri), at 30-60 °C affording the corresponding alkyl cyclohex-1-enyl ethers, ROC6H9, in 30-140% yield on palladium both under argon and under air; benzene is inert under the reaction conditions, sodium tert-butoxide does not enter the hydrocarbon alkoxylation.

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Article information

DOI
https://doi.org/10.1070/MC1997v007n05ABEH000829
Article type
Paper

Mendeleev Commun., 1997,7, 205-206

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Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with dibromobis(phosphine)palladium(II) - sodium alkoxide system

A. N. Vedernikov, M. D. Sayakhov and B. N. Solomonov, Mendeleev Commun., 1997, 7, 205 DOI: 10.1070/MC1997v007n05ABEH000829

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