Issue 6, 1997

A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

Abstract

The mechanism of dihydrogen oxidative addition to the simplest palladium cluster has been analysed within the framework of the reaction-path Hamiltonian approximation; a planar dihydride complex has been found to form without the potential energy barrier and intramolecular degenerate exchange of the protons in the complex has been investigated.

Article information

Article type
Paper

Mendeleev Commun., 1997,7, 246-248

A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

V. M. Mamaev, I. P. Gloriozov, V. V. Simonyan, E. V. Zernova, A. V. Prisyajnyuk and Y. A. Ustynyuk, Mendeleev Commun., 1997, 7, 246 DOI: 10.1070/MC1997v007n06ABEH000801

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