The synthesis of a series of cyclic organoaluminium compounds, aluminacyclopropanes, which have never previously been described, has been carried out by α>-olefin cyclometallation with EtAlCl2 in the presence of a chlorine ion acceptor, metallic magnesium and Cp2TiCl2 (Cp = ν>5-C5H5) catalyst.
U. M. Dzhemilev, A. G. Ibragimov, L. O. Khafizova, S. V. Rusakov and L. M. Khalilov, Mendeleev Commun., 1997, 7, 198 DOI: 10.1070/MC1997v007n05ABEH000791
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