The synthesis of pyrimidiniumolates with a thiophene unit (3a–c) is reported. The electrooxidation of 3a leads to a conductive polymer. Some quantum chemical data for 3a–c and the parent system 5 are given [semiempirical calculations (AM1, PM3), ab initio data and density functional theoretical results].
P. Laackmann, A. Koch and W. Friedrichsen, J. Mater. Chem., 1997, 7, 2205 DOI: 10.1039/A704922F
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