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Issue 2, 1997
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Regioselectivity in the Hydroboration of Steroidal Δ3-Allylic Alcohols†

Abstract

The presence of an allylic 5α-hydroxy group in an androst-3-ene increases the proportion of addition of a borane to the adjacent C-4 compared to the unsubstituted steroid and directs the addition to the face of the alkene anti to the hydroxy group with stereochemical effects that may oppose those of the C-10β-methyl group.

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Article type: Paper
DOI: 10.1039/A605946E
J. Chem. Res. (S), 1997, 56-57

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    Regioselectivity in the Hydroboration of Steroidal Δ3-Allylic Alcohols†

    M. Alam, J. R. Hanson, M. Liman and S. Nagaratnam, J. Chem. Res. (S), 1997, 56
    DOI: 10.1039/A605946E

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