Thermodynamic study of the binary mixture trichloromethane–1,2-epoxybutane
Abstract
A previously reported ‘chemical’ model proposes that
most strongly non-ideal binary mixtures can be described as consisting
of both simple chemical species and their associates. FTIR
spectroscopy indicates that the title mixture can be considered to
consist mainly of CHCl
3
, C
4
H
8
O,
CHCl
3
·C
4
H
8
O, and
(CHCl
3
)
2
. Comparison between experimental excess
enthalpies and those calculated using the model indicates that such a
composition provides a viable description of the mixture.
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