Issue 23, 1997
From the journal:

Journal of the Chemical Society, Dalton Transactions

Unprecedented N,S,O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H2L2) bridging two rhodium(I) centres: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(µ-L2-κN′∶κO,S)Rh(PPh3)(CO)]

Gerdus Kemp,   Andreas Roodt,   Walter Purcell  and  Klaus R. Koch  

Abstract

Reaction of [Rh(CO)2Cl]2 with N-benzoyl-N ′-phenylthiourea (H2L2) followed by PPh3 resulted in an unprecedented tridentate (κN ′∶κO,S) bonding mode of the doubly deprotonated anion of N-benzoyl-N ′-phenylthiourea to yield a dinuclear rhodium(I) complex [(PPh3)2(CO)Rh(µ-L2-κN ′∶κO,S)Rh(PPh3)(CO)]·(CH3)2CO, the structure of which was determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/A705887J
Article type
Paper

J. Chem. Soc., Dalton Trans., 1997, 4481-4484

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Unprecedented N,S,O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H2L2) bridging two rhodium(I) centres: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(µ-L2-κN′∶κO,S)Rh(PPh3)(CO)]

G. Kemp, A. Roodt, W. Purcell and K. R. Koch, J. Chem. Soc., Dalton Trans., 1997, 4481 DOI: 10.1039/A705887J

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