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Issue 22, 1997
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A new two-dimensional manganese(II)–azide polymer. Synthesis, structure and magnetic properties of [{Mn(minc)2(N3)2}n] (minc = methyl isonicotinate)

Abstract

A new two-dimensional manganese compound showing µ1,3-azido bridges has been synthesized and structurally characterised. The complex [{Mn(minc)2(N3)2}n], where minc corresponds to methyl isonicotinate, crystallises in the monoclinic system, space group P21/c, a = 12.424(5), b = 8.496(3), c = 8.399(4) Å, β = 96.41(3)° and Z = 2. Magnetic measurements show behaviour typical of a two-dimensional Heisenberg antiferromagnet with J = –2.24(2) cm–1. Low-temperature properties are discussed in comparison with those of some molecular magnets of the [{MnL2(N3)2}n] series.

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Article type: Paper
DOI: 10.1039/A702214J
J. Chem. Soc., Dalton Trans., 1997, 4431-4434

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    A new two-dimensional manganese(II)–azide polymer. Synthesis, structure and magnetic properties of [{Mn(minc)2(N3)2}n] (minc = methyl isonicotinate)

    A. Escuer, R. Vicente, M. A. S. Goher and F. A. Mautner, J. Chem. Soc., Dalton Trans., 1997, 4431
    DOI: 10.1039/A702214J

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