S · · ·
S Contact-assembled silver(I) complexes of
4,5-ethylenedithio-1,3-dithiole-2-thione having unique supramolecular
networks
Abstract
Two silver(I) complexes of
4,5-ethylenedithio-1,3-dithiole-2-thione
(C
5
H
4
S
5
),
[{Ag(C
5
H
4
S
5
)
3
}
ClO
4
·CH
3
CN]
2
and
[Ag(C
5
H
4
S
5
)CF
3
SO
3
]
∞
have been synthesized and characterized
crystallographically. They have unique dimeric and two-dimensional
structures respectively and are assembled by
S · · ·
S contacts. The finding of the shortest
S · · ·
S contacts (3.284 and 3.262 Å) in these complexes
indicated that the co-ordination linkage in metal complexes containing
these types of sulfur donor compounds could be expected to control the
intra- or inter-molecular interactions. The co-ordination mode of the
C
5
H
4
S
5
ligand has also been
discussed.
S contacts. The finding of the shortest
S · · ·
S contacts (3.284 and 3.262 Å) in these complexes
indicated that the co-ordination linkage in metal complexes containing
these types of sulfur donor compounds could be expected to control the
intra- or inter-molecular interactions. The co-ordination mode of the
C
5
H
4
S
5
ligand has also been
discussed.
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