Homoleptic tris(diacetoneglucose)phosphite as a novel entry into chiral phosphorus derivatives in organometallic chemistry
Abstract
A novel chiral C
3
phosphite P(odag)
3
(odag = 1,2∶5,6-di-O-isopropylidene-
α-D-glucofuranoside) has been synthesized on a large
scale; when treated with Cu(CO)Cl it gave the cubane
[{CuCl[P(odag)
3
]}
4
], which is in
equilibrium with a dimeric form in solution.
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