Solvothermal synthesis and crystal structure of [NEt4]6[ {Mo3(µ3-Se)(µ-η2-Se 2)3(η2-Se2)(µ-η 2-Se5)(η1-Se5)} 2(µ-η2-Se4)]. The first trinuclear molybdenum polyselenide dimer containing two [Mo3Se7]4+ cluster cores bridged by a Se42- chain
Abstract
Two equivalent [Mo
3
Se
19
]
2-
moieties, each composed of a [Mo
3
Se
7
]
4+
cluster core, two ligating Se
5
2-
chains and
a (η
2
-Se
2
)
2-
group, are
bridged by a Se
4
2-
chain to form the
[Mo
6
Se
42
]
6-
ion.
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