Issue 19, 1997

Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium†

Abstract

All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3–}.

Article information

Article type
Paper

Chem. Commun., 1997, 1879-1880

Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium†

M. A. Beswick, J. M. Goodman, A. D. Hopkins, M. A. Paver, P. R. Raithby, A. E. H. Wheatley and D. S. Wright, Chem. Commun., 1997, 1879 DOI: 10.1039/A703979D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements