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Issue 16, 1997
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A novel pentadentate ligand2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(ii)and manganese(ii) compounds; synthesis and crystal structures of[FeL(MeCN)][ClO4]2 and[(MnL(H2O)][ClO4]2


A novel pentadentate ligand L is capable of stabilising Fe II and Mn II centres, the first of which gives a transient iron hydroperoxide species upon treatment with hydrogen peroxide.

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Article type: Paper
DOI: 10.1039/A702804K
Citation: Chem. Commun., 1997,0, 1549-1550

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    A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(ii) and manganese(ii) compounds; synthesis and crystal structures of [FeL(MeCN)][ClO4]2 and [(MnL(H2O)][ClO4]2

    M. E. de Vries, R. M. La Crois, G. Roelfes, H. Kooijman, A. L. Spek, R. Hage and B. L. Feringa, Chem. Commun., 1997, 0, 1549
    DOI: 10.1039/A702804K

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