The first highly enantioselective catalytic hetero-Diels–Alder reaction of various aliphatic and aromatic ketones with an activated conjugated diene catalysed by chiral copper(II) complexes with enantiomeric excesses up to 99% is presented.
M. Johannsen and S. Yao, Chem. Commun., 1997, 2169 DOI: 10.1039/A706463B
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