SCHEDULED MAINTENANCE
The carbocyclic analogue 11 of nikkomycin C 1 is prepared by a sequence involving allylic rearrangement of the imino ester adduct 3, palladium-mediated substitution of the allylic lactone 4c with uracil bis(trimethylsilyl)ether 6, and osmylation of the double bond.
S. E. Ward, A. B. Holmes and R. McCague, Chem. Commun., 1997, 2085 DOI: 10.1039/A705825J
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