Issue 20, 1997

Stereoselective epoxidations of vinylogous esters/carbonates directed by the 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl auxiliary: a route to near stereopure tertiary alcohols bearing functional arms

Abstract

The 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl auxiliary is effective in directing the epoxidation of vinylogous esters/carbonates with dimethyldioxirane; the derived epoxides are convertible into a versatile class of 1,2,3-trifunctional chirons.

Article information

Article type
Paper

Chem. Commun., 1997, 1981-1982

Stereoselective epoxidations of vinylogous esters/carbonates directed by the 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl auxiliary: a route to near stereopure tertiary alcohols bearing functional arms

G. S. Bhatia and R. G. Pritchard, Chem. Commun., 1997, 1981 DOI: 10.1039/A705498J

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