Issue 24, 1997

Novel µ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

Abstract

Attempted dimethylation of [CpV(NC6H3Pri2-2,6)]Cl2 using Grignard reagents affords novel µ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pri2-2,6)(µ-Me)2]2(µ-Mg) 2, reveals V–(µ-Me)–Mg, V–Mg, N–Mg and C–H···Mg interactions.

Article information

Article type
Paper

Chem. Commun., 1997, 2345-2346

Novel µ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

M. C. W. Chan, V. C. Gibson, J. M. Cole and J. A. K. Howard, Chem. Commun., 1997, 2345 DOI: 10.1039/A705256A

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