Methyltrioxorhenium has been supported on silica functionalized with polyether tethers; in the absence of an organic solvent, this catalytic assembly catalysed the epoxidation of alkenes with 30% aqueous H2O2 in high selectivity compared to the ring opening products observed in homogeneous media.
R. Neumann and T. Wang, Chem. Commun., 1997, 1915 DOI: 10.1039/A704496H
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