Issue 21, 1997
From the journal:

Chemical Communications

Stereochemistry of the methyl→methylene elimination in the enzyme-catalysed cyclization of geranyl diphosphate to (4S)-limonene

Robert M. Coates,   Charles S. Elmore,   Robert M. Coates,   Rodney B. Croteau,   David C. Williams,   Charles S. Elmore,   Rodney B. Croteau,   Hiromi Morimoto  and  Philip G. Williams  

Abstract

The cyclization of (R)-[9-2H1,3H1]geranyl diphosphate catalysed by a recombinant form of (4S)-limonene synthase from spearmint leaf (Mentha spicata) is terminated predominantly by re-facial, anti proton elimination at the cis methyl group, producing (4S, 8E)-[8-2H1,3H1]limonene.

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Article information

DOI
https://doi.org/10.1039/A704370H
Article type
Paper

Chem. Commun., 1997, 2079-2080

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Stereochemistry of the methyl→methylene elimination in the enzyme-catalysed cyclization of geranyl diphosphate to (4S)-limonene

R. M. Coates, C. S. Elmore, R. M. Coates, R. B. Croteau, D. C. Williams, C. S. Elmore, R. B. Croteau, H. Morimoto and P. G. Williams, Chem. Commun., 1997, 2079 DOI: 10.1039/A704370H

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