A sulfur nitrogen triple, double and single bond in one ligand:
synthesis and structure of
[Co{N![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
SF2–N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
S(O)F2}
4][AsF6]2·SO2
Abstract
NSF
2
NS(O)F
2
reacts quantitatively with
[Co(SO
2
)
n
][AsF
6
]
2
to
give
[Co{NSF
2
–NS(O)F
2
}
4
][AsF
6
]
2
·SO
2
; X-ray
structure analysis confirms the presence of a triple, double and single
bond in the same ligand.
SF
2
–NS(O)F
2
}
4
][AsF
6
]
2
·SO
2
; X-ray
structure analysis confirms the presence of a triple, double and single
bond in the same ligand.
Please wait while we load your content...
![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e002.gif)
SF2–N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
S(O)F2}
4][AsF6]2·SO2
