Preparation and X-ray crystallographic characterisation of the
trititanate
[Ti3O(µ-OPri)3(OPri)4
{Me2C(O)CH![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C(O)CH2C(O)Me2
}], a reaction product of [Ti(OPri)4] and
propan-2-one
Abstract
Reaction of Ti(OPr
i
)
4
with propan-2-one, under
initially anhydrous conditions, yields a colourless moisture-sensitive
crystalline product which is structurally identified as the trinuclear
oxoalkoxide
[Ti
3
O{µ-OPr
i
)
3
(OPr
i
)
4
{Me
2
C(O)CHC(O)CH
2
C(O)Me
2
}] containing a coordinated C
9
ligand derived
from the condensation of propan-2-one.
C(O)CH
2
C(O)Me
2
}] containing a coordinated C
9
ligand derived
from the condensation of propan-2-one.
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![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
C(O)CH2C(O)Me2
}], a reaction product of [Ti(OPri)4] and
propan-2-one
