Homogeneous modeling of ammoxidation chemistry: nitrile formation using a soluble analogue of MoO3
Abstract
The reaction of the soluble MoO
3
analogue
[Mo
6
O
19
]
2-
with
Ph
3
P![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NCH
2
Ph replicates key features of
heterogeneous ammoxidation chemistry by producing moderate yields of
PhC![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
N through the proposed intermediacy of the benzylimido
hexamolybdate complex
[Mo
6
O
18
(NCH
2
Ph)]
2-
.
NCH
2
Ph replicates key features of
heterogeneous ammoxidation chemistry by producing moderate yields of
PhCN through the proposed intermediacy of the benzylimido
hexamolybdate complex
[Mo
6
O
18
(NCH
2
Ph)]
2-
.
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