Issue 19, 1997

Modelling the active sites of heterogeneous titanium-centred epoxidation catalysts with soluble silsesquioxane analogues

Abstract

By synthesising and structurally characterising new soluble titanosilsesquioxanes, and by following the dynamics of epoxidation of cyclohexene in their presence, the tripodally anchored TiIV active sites in Ti–SiO2 heterogeneous catalysts are modelled structurally and catalytically.

Article information

Article type
Paper

Chem. Commun., 1997, 1847-1848

Modelling the active sites of heterogeneous titanium-centred epoxidation catalysts with soluble silsesquioxane analogues

T. Maschmeyer, M. C. Klunduk, C. M. Martin, D. S. Shephard, B. F. G. Johnson, T. Maschmeyer and J. Meurig Thomas, Chem. Commun., 1997, 1847 DOI: 10.1039/A703642F

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