SCHEDULED MAINTENANCE
Intramolecular proton transfer from a cation to the associated, structurally characterised, hydride-containing anion [(PPh3)2(H)Ru(µ-H)(µ-Cl)2Ru(H)(PPh 3)2]- to give an η2-H2 complex
Abstract
The previously unknown, dinuclear, ionic ruthenium(II)
species
[Hdma][(PPh
3
)
2
(H)Ru(µ-H)(µ-Cl)
2
Ru(
H)-(PPh
3
)
2
]·dma 1 (dma =
N,N-dimethylacetamide) is characterised by X-ray crystallography;
in solution, intramolecular proton transfer from the cation to the anion
gives the known molecular hydrogen complex
[(PPh
3
)
2
(η
2
-H
2
)Ru(µ-H)
(µ-Cl)
2
Ru(H)(PPh
3
)
2
] 2.
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