Synthesis and characterization of the first dodecanuclear M–Ag–S cage cluster: [NEt4]2[{M2Ag2S2 O2(S2C2H4)2 }3(µ6-S)]·CH2Cl2 ·MeCN (M = Mo, W)
Abstract
The first dodecanuclear heterobimetallic cage cluster with a central
µ
6
-S ligand, containing the core
[{M
2
Ag
2
-
S
2
O
2
(edt)
2
}
3
(µ
6
-S)]
2-
(M = Mo, W; H
2
edt =
ethane-1,2-dithiol), is synthesized and characterized; the average
Ag–µ
6
-S bond length of the core
[{Mo(W)
2
Ag
2
-
S
2
O
2
(edt)
2
}
3
(µ
6
-S)]
2-
is 2.528 (2.531) Å.
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