Issue 18, 1997

Intramolecular migration of [Pt(dien)]2+ (dien = 1,5-diamino-3-azapentane) from sulfur to imidazole-N1 in histidylmethionine (his-metH)

Abstract

HPLC and NMR investigations of the kinetics of competitive binding by neighbouring side chains in his-metH demonstrate that at pH > 6 initial S coordination is followed by slow isomerization to an imidazole-N 1 bound complex through a dinuclear intermediate [{Pt(dien)} 2 (his-metH-1κN 1 :2κS)] 4+

Article information

Article type
Paper

Chem. Commun., 1997, 1737-1738

Intramolecular migration of [Pt(dien)]2+ (dien = 1,5-diamino-3-azapentane) from sulfur to imidazole-N1 in histidylmethionine (his-metH)

C. D. W. Fröhling and W. S. Sheldrick, Chem. Commun., 1997, 1737 DOI: 10.1039/A702904G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements