Issue 13, 1997

Palladium-catalysed sequential carboxylation–alkoxycarbonylation of acetylenic amines

Abstract

Carbon dioxide and carbon monoxide react in sequence in an intramolecular carboxy–carbonylation reaction of N-alkyl-substituted dialkylpropynylamines, under the catalytic action of palladium iodide–potassium iodide in methanol in the presence of oxygen.

Article information

Article type
Paper

Chem. Commun., 1997, 1209-1210

Palladium-catalysed sequential carboxylation–alkoxycarbonylation of acetylenic amines

A. Bacchi, G. Paolo Chiusoli, M. Costa, B. Gabriele, C. Righi and G. Salerno, Chem. Commun., 1997, 1209 DOI: 10.1039/A702822I

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