Issue 17, 1997

Reaction of phosphaacetylenes ButC[triple bond, length as m-dash]P and 1-AdC[triple bond, length as m-dash]P with (PhSe)2–XeF2: first examples of vicinal bis-selenenylation (at P and C) to form novel phosphaalkenes

Abstract

tert-Butyl- and 1-adamantyl-phosphaacetylenes (2 equiv.) react with (PhSe) 2 –XeF 2 (→2 PhSeF) to give novel phosphaalkenes by vicinal bis-phenylselenenylation (at P and C), in contrast to acetylenes which undergo fluoroselenenylation.

Article information

Article type
Paper

Chem. Commun., 1997, 1641-1642

Reaction of phosphaacetylenes ButC[triple bond, length as m-dash]P and 1-AdC[triple bond, length as m-dash]P with (PhSe)2–XeF2: first examples of vicinal bis-selenenylation (at P and C) to form novel phosphaalkenes

K. K. Laali, W. Fiedler and M. Regitz, Chem. Commun., 1997, 1641 DOI: 10.1039/A702737K

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