Carbon dioxide activation: synthesis and characterization of a cadmium(ii) dinuclear complex with a novel µ-carbonato bridge
Abstract
The cadmium(II) complex of
N′-isopropyl-2-methylpropane-1,2-diamine (npda),
[Cd(npda)
3
][ClO
4
]
2
1 in aqueous methanol
absorbs CO
2
from air to form a cadmium(II) dinuclear
complex,
[Cd(npda)
4
(CO
3
)(H
2
O)][ClO
4
]
2
·H
2
O 2, the first ever example of a
µ-carbonato cadmium(II) diamine complex which is
characterized by elemental analysis, IR and crystal structure
determination.
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