Thioacyl complexes of molybdenum and tungsten
Abstract
The reactions of a range of alkylidyne complexes of molybdenum and
tungsten [M(![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CR)L
n
] with 2-methylthiirane
provide the first thioacyl complexes
[M(η
2
-SCR)L
n
] of these elements, which
serve as precursors for complexes bearing dithiocarboxylate,
thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and
thioacyl-bridged binuclear complexes.
CR)L
n
] with 2-methylthiirane
provide the first thioacyl complexes
[M(η
2
-SCR)L
n
] of these elements, which
serve as precursors for complexes bearing dithiocarboxylate,
thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and
thioacyl-bridged binuclear complexes.
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