One-dimensional alignment of organometallic donor–acceptor
compounds via coordination polymerization. Synthesis and
structures of
[W(![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CC6H4X-4)(OBut)3]
∞ (X = NMe2, SMe)
Abstract
Metal–alkylidyne complexes of the type
W(CC
6
H
4
X-4)(OBu
t
)
3
(X
= NMe
2
, SMe), which are analogues of classic organic
donor–acceptor compounds, form infinite-chain structures in the
solid state through weak intermolecular dative bonds between the tungsten
and donor atoms.
CC
6
H
4
X-4)(OBu
t
)
3
(X
= NMe
2
, SMe), which are analogues of classic organic
donor–acceptor compounds, form infinite-chain structures in the
solid state through weak intermolecular dative bonds between the tungsten
and donor atoms.
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![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e002.gif)
CC6H4X-4)(OBut)3]
∞ (X = NMe2, SMe)
