Issue 10, 1997

X-Ray crystallographic structure of Ga8(pz)12O4Cl4·2thf: a novel gallium pyrazololate complex with a Ga4O4 core

Abstract

The reaction of Na[MeGa(pz) 3 ] with GaCl 3 leads to the formation of the novel cubane Ga 8 (pz) 12 O 4 Cl 4 ·2thf 1, and not the expected product [{MeGa(pz) 3 } 2 Ga][GaCl 4 ]; the ease with which 1 forms is illustrated by its formation in a subsequent reaction of Na[MeGa(pz) 3 ] with GaCl 3 .

Article information

Article type
Paper

Chem. Commun., 1997, 937-938

X-Ray crystallographic structure of Ga8(pz)12O4Cl4·2thf: a novel gallium pyrazololate complex with a Ga4O4 core

M. V. Capparelli, P. Hodge and B. Piggott, Chem. Commun., 1997, 937 DOI: 10.1039/A701044C

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