Synthesis and structural characterisation of two- and three-dimensional fluorinated indium phosphates
Abstract
Hydrothermal synthesis of two new fluorinated indium phosphates
[InPO
4
F(Hen)] and
[In
5
P
4
F
3
O
16
(en)
3
(O
H
2
)
2
] is carried out in the system
In
2
O
3
–P
2
O
5
–en
–HF–H
2
O (en = ethylenediamine); these have two- and
three-dimensional inorganic frameworks respectively, with the latter
having ten-membered ring channels spanned by coordinated en; the fluorides
bridge exclusively between indium ions and may be linear or bent.
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