Issue 8, 1997

Activation of CO2 by laser-ablated group 6 metal atoms

Abstract

The primary reaction products of laser-ablated group 6 atoms with CO 2 prove to be the insertion products OMCO and O 2 M(CO) 2 (M = Cr, Mo, W) which are isolated in argon matrices and identified by the effects of isotopic substitution on their IR spectra.

Article information

Article type
Paper

Chem. Commun., 1997, 777-778

Activation of CO2 by laser-ablated group 6 metal atoms

P. F. Souter and L. Andrews, Chem. Commun., 1997, 777 DOI: 10.1039/A700360I

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