Issue 6, 1997

Chiral discrimination in the oxidation of ferrocenes by cytochrome c peroxidase

Abstract

Cytochrome c peroxidase shows a two-fold difference in its reaction rate with enantiomers of a chiral ferrocene; the enantiomeric selectivity is reversed by a single site specific change in the surface charge of the enzyme.

Article information

Article type
Paper

Chem. Commun., 1997, 517-518

Chiral discrimination in the oxidation of ferrocenes by cytochrome c peroxidase

S. J. Sadeghi, G. Gilardi, G. Nicolosi and A. E. G. Cass, Chem. Commun., 1997, 517 DOI: 10.1039/A700243B

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