Issue 6, 1997

Reaction control and potential tuning in a supercritical fluid

Abstract

A maximum is found in the ratio of endo- to exo- products vs. density in the Diels–Alder reaction between cyclopentadiene and methyl acrylate in supercritical carbon dioxide and is explained by the adjustment of the position of the nearest-neighbour solvent molecules with respect to the transition states.

Article information

Article type
Paper

Chem. Commun., 1997, 595-596

Reaction control and potential tuning in a supercritical fluid

A. A. Clifford, K. Pople, W. J. Gaskill, K. D. Bartle and C. M. Rayner, Chem. Commun., 1997, 595 DOI: 10.1039/A608066I

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