Issue 3, 1997
From the journal:

Chemical Communications

Photochemistry of acetone in the presence of exocyclic olefins: an unexpected competition between the photo-Conia and Paternò–Büchi reactions

Wen-Sheng Chung  and  Chia-Chin Ho  

Abstract

When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 ± 0.01) rather than exhibiting the expected Paternò–Büchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.

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Article information

DOI
https://doi.org/10.1039/A607415D
Article type
Paper

Chem. Commun., 1997, 317-318

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Photochemistry of acetone in the presence of exocyclic olefins: an unexpected competition between the photo-Conia and Paternò–Büchi reactions

W. Chung and C. Ho, Chem. Commun., 1997, 317 DOI: 10.1039/A607415D

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