Rings and linear polymers formed by addition of silver perchlorate
to
trans-[Pt(C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CR)2(PMe2Ph)2
] (R = But, H)
Abstract
Addition of AgClO
4
to
trans-[Pt(CCR)
2
(PMe
2
Ph)
2
] (R = Bu
t
, H) gives 1:1 adducts of the general formula
trans-[PtAg(ClO
4
)(µ-CCR)
2
(PMe
2
Ph)
2
] which are cyclic dimers when R =
Bu
t
(ClO
4
-
not coordinated) or
linear polymers when R = H (ClO
4
-
coordinated
to silver).
CR)
2
(PMe
2
Ph)
2
] (R = Bu
t
, H) gives 1:1 adducts of the general formula
trans-[PtAg(ClO
4
)(µ-CCR)
2
(PMe
2
Ph)
2
] which are cyclic dimers when R =
Bu
t
(ClO
4
-
not coordinated) or
linear polymers when R = H (ClO
4
-
coordinated
to silver).
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![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e002.gif)
CR)2(PMe2Ph)2
] (R = But, H)
