[Fe3Cu(SPri)6Cl3] 2-: a novel mixed-metal thiolate complex with a ‘truncated’ adamantane-like structure
Abstract
Reaction of
[Fe
2
(SPr
i
)
6
]
2-
with
FeCl
2
and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran
gives the complex anion
[Fe
3
Cu(SPr
i
)
6
Cl
3
]
2
-
which contains a Fe
3
Cu pyramidal core; the
structure, magnetic properties and the solution
1
H NMR spectrum
are reported.
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