A reductive rearrangement of iron acetylide hydride complexes
Abstract
Iron acetylide hydride complexes of the type
[Fe(H)(C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CR)(dmpe)
2
] [dmpe =
1,2-bis(dimethylphosphino)ethane] react with anions in a methanol solution
to form substituted alkenyl complexes; the crystal structure of
trans-FeN
3
(CH![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CHPh)(dmpe)
2
] is
presented.
CR)(dmpe)
2
] [dmpe =
1,2-bis(dimethylphosphino)ethane] react with anions in a methanol solution
to form substituted alkenyl complexes; the crystal structure of
trans-FeN
3
(CHCHPh)(dmpe)
2
] is
presented.
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