Issue 1, 1997

Perfluorovinyl–metal derivatives: a new one-pot synthesis

Abstract

The one-pot reaction of the CFC replacement 1,1,1,2-tetrafluoroethane (CF 3 CFH 2 , HFC-134a) with 2 equiv. of butyllithium in diethyl ether at -78 °C followed by the addition of main-group or transition-metal halides results in good yields of the corresponding metal–perfluorovinyl compounds of high purity.

Article information

Article type
Paper

Chem. Commun., 1997, 139-140

Perfluorovinyl–metal derivatives: a new one-pot synthesis

K. K. Banger, A. K. Brisdon and A. Gupta, Chem. Commun., 1997, 139 DOI: 10.1039/A605732B

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