Issue 12, 1996

Solid-state structure of 1,2-dimethoxybenzene (veratrole) and related methoxybenzenes. X-Ray crystallography and 13C nuclear magnetic resonance tensor analysis

Abstract

We present here the single crystal X-ray structure of 1,2-dimethoxybenzene which reveals the methoxy groups to be trans and twisted out of the plane by –5.0 and 8.6°. Using variable spinning rate 13C CP MAS NMR spectroscopy, the principal shielding tensors were measured for anisole, 1,2-dimethoxybenzene, 1,4-dimethoxybenzene and 1,3,5-trimethoxybenzene. From this work the principal elements were obtained for static benzene (σ11= 222, σ22= 147 and σ33= 14) and for the substituent chemical shift of a planar methoxy group. The ab initio tensors of 1,2-dimethoxybenzene were calculated by the GIAO and LORG methods using the X-ray data as input. The CP MAS spectrum of 1,3-dimethoxybenzene reveals that this molecule adopts the asymmetric planar conformation.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1996, 2687-2693

Solid-state structure of 1,2-dimethoxybenzene (veratrole) and related methoxybenzenes. X-Ray crystallography and 13C nuclear magnetic resonance tensor analysis

M. Gerzain, G. W. Buchanan, A. B. Driega, G. A. Facey, G. Enright and R. A. Kirby, J. Chem. Soc., Perkin Trans. 2, 1996, 2687 DOI: 10.1039/P29960002687

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