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Issue 8, 1996
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Absolute rate constants for abstraction of chlorine from three chlorinating agents by alkyl radicals

Abstract

Using the cyclopropylcarbinyl → homoallyl free radical clock, absolute rate constants for the abstraction of chlorine from molecular chlorine (Cl2), tert-butyl hypochlorite (ButOCl) and N-chloro-3,3-dimethylglutarimide (NCG) have been determined (kCl2)= 3.0 × 1010, kButOCl= 2.6 × 109 and kNCG= 3.6 × 107, all in l mol–1 s–1).

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J. Chem. Soc., Perkin Trans. 2, 1996, 1775-1779
Article type
Paper

Absolute rate constants for abstraction of chlorine from three chlorinating agents by alkyl radicals

J. M. Tanko and J. F. Blackert, J. Chem. Soc., Perkin Trans. 2, 1996, 1775
DOI: 10.1039/P29960001775

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