Issue 5, 1996

The Hammett equation and Snyder theory as a criterion for adsorption of a functional group under liquid–solid chromatography

Abstract

The application of the Hammett equation in a suitable form to TLC separations on silica of aromatic aldehydes, 4-X–C6H4–Y, and related 5-arylidene thiazolidine-2, 4-diones has shown some substantial deviations to higher values from the correlation lines which are considered on the basis of Snyder theory as a proof for adsorption of the corresponding group X (from a substituent, it becomes a new adsorption centre Y′). Based on this criterion, the data of this paper and previous papers support the adsorption of group X when it is 3-OH, 4-OH, 3-NO2, 4-NO2 and 3-OCH3. The adsorption of X seems to occur when its adsorptivity is similar to that of Y and the electronic interaction between X and Y is of limited importance.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1996, 961-964

The Hammett equation and Snyder theory as a criterion for adsorption of a functional group under liquid–solid chromatography

M. Palamareva and S. Chorbadjiev, J. Chem. Soc., Perkin Trans. 2, 1996, 961 DOI: 10.1039/P29960000961

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