Issue 22, 1996
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

π-Face selectivities in nucleophilic additions to 2-endo-arylnorbornan-7-ones: the role of through-space electrostatic interactions

Goverdhan Mehta,   Faiz Ahmed Khan,   Narinder Mohal,   I. N. Narayan Namboothiri,   P. Kalyanaraman  and  Jayaraman Chandrasekhar  

Abstract

Experimental diastereoselectivities in hydride reduction of 2-endo-arylnorbornan-7-ones and computed transition state energetics reveal that the facial selectivity in these systems is predominantly determined by repulsions between the approaching nucleophile and the electron cloud of the aryl ring.

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Article information

DOI
https://doi.org/10.1039/P19960002665
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1996, 2665-2667

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π-Face selectivities in nucleophilic additions to 2-endo-arylnorbornan-7-ones: the role of through-space electrostatic interactions

G. Mehta, F. A. Khan, N. Mohal, I. N. N. Namboothiri, P. Kalyanaraman and J. Chandrasekhar, J. Chem. Soc., Perkin Trans. 1, 1996, 2665 DOI: 10.1039/P19960002665

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