Isoquinolin-1(2H)-one undergoes regiospecific and highly stereoselective (2π+ 2π) photocycloaddition with electron deficient ethenes at wavelengths longer than 290 nm: with 254 nm radiation, the adducts rearrange to N-vinylisoindolinones and undergo retroaddition.
N. Al-Jalal, M. G. B. Drew and A. Gilbert, J. Chem. Soc., Perkin Trans. 1, 1996, 965 DOI: 10.1039/P19960000965
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