Issue 7, 1996

Synthesis and characterization of bis[1.1.1]orthocyclophano-18-crown-6 compounds

Abstract

Two novel macrocyclic compounds 5S and 5A combining an 18-crown-6 and two cyclotriveratrylenes were synthesized by means of two methods from dibenzo-18-crown-6. The conformational isomers were separated using complexation with KSCN and their stereostructures were determined on the basis of 1H NMR spectroscopic and thermal equilibration studies.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1996, 741-745

Synthesis and characterization of bis[1.1.1]orthocyclophano-18-crown-6 compounds

H. Hara, S. Watanabe, M. Yamada and O. Hoshino, J. Chem. Soc., Perkin Trans. 1, 1996, 741 DOI: 10.1039/P19960000741

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